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| 编织芳基网络聚合物负载Rh催化剂上高碳烯烃氢甲酰化反应性能 | |
| 引用本文： | 姜淼,丁云杰,严丽,宋宪根,林荣和. 编织芳基网络聚合物负载Rh催化剂上高碳烯烃氢甲酰化反应性能[J]. 催化学报, 2014, 35(9): 1456-1464. DOI: 10.1016/S1872-2067(14)60068-1 |
| 作者姓名： | 姜淼 丁云杰 严丽 宋宪根 林荣和 |
| 作者单位： | a 中国科学院大连化学物理研究所洁净能源国家实验室(筹), 辽宁大连116023; b 中国科学院大连化学物理研究所催化基础国家重点实验室, 辽宁大连116023; c 中国科学院大学, 北京100049 |
| 摘 要： | 考察了编织芳基网络聚合物（KAPs）负载的Rh催化剂（Rh/KAPs）在高碳烯烃氢甲酰化反应中的催化性能. 结果表明，三苯基膦-苯基底KAPs负载Rh催化剂（Rh/KAPs-1）具有优异的高碳烯烃氢甲酰化反应活性，产物醛收率显著高于Rh/SiO2催化剂. 傅里叶变换红外光谱、热重、氮气吸附-脱附、X射线衍射、透射电子显微镜、13C核磁共振和31P核磁共振结果显示，Rh/KAPs-1催化剂具有优异的热稳定性及大的比表面积和多级孔道结构，Rh颗粒处于高度分散状态，并可在反应过程中形成均相催化活性物种. |
| 关 键 词： | 三苯基膦 编织芳基网络聚合物 铑 多相催化剂 高碳烯烃氢甲酰化 |
| 收稿时间： | 2014-01-23 |
Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins |
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| Miao Jiang,Yunjie Ding,Li Yan,Xiangen Song,Ronghe Lin. Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins[J]. Chinese Journal of Catalysis, 2014, 35(9): 1456-1464. DOI: 10.1016/S1872-2067(14)60068-1 | |
| Authors: | Miao Jiang Yunjie Ding Li Yan Xiangen Song Ronghe Lin |
| Affiliation: | a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China; b State Key Laboratory for Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China; c University of Chinese Academy of Sciences, Beijing 100049, China |
| Abstract: | Rh catalysts supported on knitting aryl network polymers (Rh/KAPs) were prepared for the hydroformylation of higher olefins. Rh catalysts supported on triphenylphosphine-benzene-base polymers (Rh/KAPs-1) showed higher activity for the higher olefins than Rh/SiO2 catalysts. Fourier transform infrared spectroscopy, thermogravimetry, N2 adsorption-desorption, X-ray diffraction, transmission electron microscopy, 13C NMR, and 31P NMR showed that the Rh/KAPs-1 catalysts have high thermal stability, high surface area, hierarchical porosity, highly dispersed Rh nanoparticles, and in situ formed homogeneous active species during the reaction. |
| Keywords: | Triphenylphosphine Knitting aryl network polymer Rhodium Heterogeneous catalyst Hydroformylation of higher olefins |
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