A one-pot synthesis to [(Me3Si)3SiSb]4; a potential precursor for Sb42- |
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| Authors: | García Felipe Hopkins Alexander D Kowenicki Richard A McPartlin Mary Tesa Yolanda |
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| Institution: | Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UKCB2 1EW. |
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| Abstract: | The reaction of (Me(3)Si)(3)SiKmiddle dot]18-crown-6 with SbCl(3)(3 : 1 equiv.) provides a simple route to the title complex (Me(3)Si)(3)SiSb](4). The potassium base initially acts as a nucleophile and then as a coupling agent, forming Sb-Sb bonds. |
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