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Orthogonal array design for the optimization of hollow fiber protected liquid-phase microextraction of salicylates from environmental waters
Authors:Zhang Cong  Ye Lei  Xu Li
Affiliation:aState Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China;bCollege of Chemistry and Chemical Engineering, Graduate University of Chinese Academy of Sciences, Beijing 100049, China
Abstract:A new fluorescent probe for the detection of F (TBA+ and Na+ salts) has been developed, which is based on a desilylation triggered chromogenic reaction in water. This probe exhibits excellent F ion selectivity as well as significant color changes visible to the naked eye at the concentration of 1.5 mg L−1, the WHO recommended level of F ions in drinking water. This new carbohydrate modified probe can be used directly in aqueous medium without using organic co-solvents. Furthermore, the probe presents high sensitivity and selectivity for the imaging of F ions in HepG2 cells.
Keywords:Fluorescent probes   Fluoride ions   Carbohydrates   Sensors   Imaging agents
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