Association Model and Its Representation of Phase Equilibria and Excess Enthalpies of Alcohol, Aniline, and Acetonitrile Mixtures |
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| Authors: | Isanu Nagata Kazuhiro Tamura Kaoru Tada Fumihiro Nishikawa |
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| Institution: | (1) Department of Chemistry and Chemical Engineering, Division of Physical Sciences, Kanazawa University, 40-20, Kodatsuno 2-chome, Kanazawa, Ishikawa, 920-8667, Japan |
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| Abstract: | An association model is presented to describe vapor–liquid equilibria,liquid–liquid equilibria, and excess enthalpies of binary and ternary liquid solutionscontaining alcohols, aniline, and/or acetonitrile using the concepts of linearself-association of associated components and of solvation between unlike molecules.Calculated results also show that the model works well in representing thethermodynamic properties for alcohol + aniline, alcohol + acetonitrile, andalcohol + alcohol mixtures. |
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| Keywords: | Acetonitrile alcohols aniline association model binary systems excess enthalpies liquid– liquid equilibria molecular complexation ternary systems vapor– liquid equilibria |
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