A concise stereoselective synthesis of (-)-erycibelline |
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| Authors: | Zhang Zhao-Lan Nakagawa Shinpei Kato Atsushi Jia Yue-Mei Hu Xiang-Guo Yu Chu-Yi |
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| Affiliation: | Beijing National Laboratory for Molecular Science (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100191, China. |
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| Abstract: | (-)-Erycibelline, the dihydroxynortropane alkaloid isolated from Erycibe elliptilimba Merr. et Chun., was synthesized using a cyclic nitrone as advanced intermediate, wherein the key step was the SmI(2)-induced intramolecular reductive coupling of cyclic nitrone with aldehyde which resulted in good yield and stereoselectivity. |
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