Electrolyte tuning of electrode potentials: the one electron vs. two electron reduction of anthraquinone-2-sulfonate in aqueous media |
| |
| Authors: | Li Qian Batchelor-McAuley Christopher Lawrence Nathan S Hartshorne Robert S Compton Richard G |
| |
| Affiliation: | Department of Chemistry, Physical and Theoretical Chemistry Laboratory, Oxford University, South Parks Road, Oxford, OX1 3QZ, United Kingdom. |
| |
| Abstract: | The electrode potentials of quinone redox centres in aqueous solutions can be tuned by varying the electrolyte cation identity. The phenomenon is due to the ion pairing effect of the tetra-n-butylammonium cation with the semiquinone intermediate species. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
