Z-formamidoximes in molecular folding and macrocycles |
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Authors: | Zhao Weiwen Wang Ruiyao Petitjean Anne |
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Institution: | Department of Chemistry, Queen's University, Kingston, ON K7L3N6, Canada. |
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Abstract: | The formamidoxime configurational Z isomer coupled with the pyridylbiscarboxamide conformational codon were used to fold planar, curved structures. When embedded into macrocycles, this folded motif promotes dimerization through π-π stacking and hydrogen-bonding and the formation of tubules akin to molecular channels in the solid state. |
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