| 硼酸盐晶体及其溶液结构研究现状 |
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| 引用本文： | 戈海文,邓天龙,姚燕,高洁. 硼酸盐晶体及其溶液结构研究现状[J]. 广东微量元素科学, 2011, 18(1): 17-23 |
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| 作者姓名： | 戈海文 邓天龙 姚燕 高洁 |
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| 作者单位： | 戈海文,GE Haiwen(成都理工大学材料与化学化工学院,四川,成都,610059;中科院盐湖资源与化学重点实验室,中科院盐湖所,青海,西宁,810008);邓天龙,DENG Tianlong(成都理工大学材料与化学化工学院,四川,成都,610059;中科院盐湖资源与化学重点实验室,中科院盐湖所,青海,西宁,810008;天津市海洋资源与化学重点实验室,天津科技大学,天津,300457);姚燕,高洁,YAO Yan,GAO Jie(中科院盐湖资源与化学重点实验室,中科院盐湖所,青海,西宁,810008) |
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| 基金项目： | 国家自然科学基金重点和面上项目 |
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| 摘 要： | 硼酸盐结构十分复杂,主要针对硼酸盐晶体结构和硼酸盐水溶液结构问题,总结了水合硼酸盐晶体结构及其结晶行为,归纳了硼酸盐水溶液中硼酸盐的主要存在形式及其结构研究,并侧重介绍和评价了电导/电势滴定、红外(IR)、拉曼光谱(Raman)、11B核磁共振等方法在硼酸盐溶液结构研究方面的进展,指出了未来的发展方向.
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| 关 键 词： | 硼酸盐 硼酸盐溶液 核磁共振 红外 拉曼光谱 |
Progresses on Structures of Crystallized Borate Salts and Their Solutions |
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| GE Haiwen,DENG Tianlong,YAO Yan,GAO Jie. Progresses on Structures of Crystallized Borate Salts and Their Solutions[J]. Trace Elements Science, 2011, 18(1): 17-23 |
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| Authors: | GE Haiwen DENG Tianlong YAO Yan GAO Jie |
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| Affiliation: | 1.College of Materials,Chemistry and Chemical Engineering,Chengdu University of Technology, Chengdu 610059,China;2.CAS Key Laboratory of Salt Lakes Resources and Chemistry, Qinghai Institute of Salt Lakes at CAS,Xining 810008,China;3.Tianjin Key Laboratory of Marine Resources and Chemistry,Tianjin University of Science and Technology,Tianjin 300457,China) |
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| Abstract: | Borate structures are very complex.A review with 23 references is given the problems of the structures for borate salts and their solutions,including the crystallizations of borate salts and their crystallized behaviors and the structures of aqueous borates including conductance /potentiometer titration,infrared spectrum(IR),Raman spectrum(Raman),11B nuclear magnetic resonance(11B NMR).The new trend in the future is also pointed out. |
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| Keywords: | borate borate solution NMR IR Raman |
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