| 溶剂对呋喃二羧酸与Mn(Ⅱ)自组装的结构调控 |
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| 引用本文： | 陈文娴,吴耿煌,庄桂林,孔祥建,龙腊生,黄荣彬,郑兰荪.溶剂对呋喃二羧酸与Mn(Ⅱ)自组装的结构调控[J].高等学校化学学报,2011,32(3):519-526. |
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| 作者姓名： | 陈文娴 吴耿煌 庄桂林 孔祥建 龙腊生 黄荣彬 郑兰荪 |
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| 作者单位： | 厦门大学化学化工学院, 固体表面物理化学国家重点实验室, 厦门 361005 |
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| 基金项目： | 国家自然科学基金，国家"九七三"计划项目 |
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| 摘 要： | 以呋喃二羧酸 (H2FDC) 与 Mn(II) 为研究对象，通过改变溶剂体系分别得到了化合物 Mn(FDC)(H2O)3 (1) 和化合物 NH4]2?Mn3(FDC)4]?2DMF?2H2O (2). 呋喃二羧酸与 Mn(II)在DMF与水的混合溶剂中形成了具有一维链状结构的化合物1，而在DMF溶剂中则形成了具有三维开放结构的化合物2，这反应了溶剂对产物结构具有重要的影响. 变温磁化率测试及量子蒙特卡洛方法拟合都表明化合物1和2 都表现为反铁磁性.
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| 关 键 词： | 溶剂效应 金属有机框架 磁性 |
| 收稿时间： | 2010-10-13 |
Solvent Control over Structural Diversity of Two Manganese Complexes Based on Furan-2,5-dicaboxylate |
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| CHEN Wen-Xian,WU Geng-Huang,ZHUANG Gui-Lin,KONG Xiang-Jian,LONG La-Sheng,HUANG Rong-Bin,ZHENG Lan-Sun.Solvent Control over Structural Diversity of Two Manganese Complexes Based on Furan-2,5-dicaboxylate[J].Chemical Research In Chinese Universities,2011,32(3):519-526. |
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| Authors: | CHEN Wen-Xian WU Geng-Huang ZHUANG Gui-Lin KONG Xiang-Jian LONG La-Sheng HUANG Rong-Bin ZHENG Lan-Sun |
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| Institution: | State Key Laboratory of Physical Chemistry of Solid Surface, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China |
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| Abstract: | Two complexes, namely, Mn(FDC)(H2O)3(1) and H2N(CH3)2]2 · Mn3(FDC)4] · 2DMF·H2O(2) (H2 FDC = Furan-2,5-dicarboxylic acid), were synthesized via the solvothermal reaction of manganese ( II ) chloride and furan-2,5-dicarboxylate acid under different solvent conditions. Single-crystal analysis reveals that one-dimensional complex I was obtained when the reaction was carried out in DMF/H2 O, while three-dimensional complex 2 was synthesized when the reaction was carried out in DMF. Variable-temperature magnetic measurements and Quantum Monte Carlo(QMC) simulation indicate that both the complexes exhibit antiferromagnetic characteristic. |
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| Keywords: | Solvent effect Metal-organic framework Magnetism |
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