| 乌头类双酯型生物碱组分转化为单酯水解型及脂型生物碱组分的研究 |
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| 引用本文： | 刘文龙,刘志强,宋凤瑞,刘淑莹.乌头类双酯型生物碱组分转化为单酯水解型及脂型生物碱组分的研究[J].高等学校化学学报,2011,32(3):717-720. |
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| 作者姓名： | 刘文龙 刘志强 宋凤瑞 刘淑莹 |
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| 作者单位： | 1. 中国科学院长春应用化学研究所长春质谱中心, 长春 130022;
2. 中国科学院研究生院, 北京 100049 |
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| 基金项目： | 国家"九七三"计划中医理论专项，国家自然科学基金 |
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| 摘 要： | 建立了乌头类双酯型生物碱组分专一的转化为单酯水解型生物碱组分和脂型生物碱组分的方法，其转化率在90%以上，应用电喷雾多级串联质谱方法监测反应进程并对反应产物进行鉴定，同时可以考察反应中生成的副产物.
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| 关 键 词： | 乌头类生物碱 C19-二萜类生物碱 电喷雾质谱 转化 |
| 收稿时间： | 2010-08-27 |
Specific Conversion of Diester-diterpenoid Aconitum Alkaloids Components into Hydrolysis Monoester-diterpenoid Alkaloids Components and Lipo-alkaloids Components |
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| LIU Wen-Long,LIU Zhi-Qiang,SONG Feng-Rui,LIU Shu-Ying.Specific Conversion of Diester-diterpenoid Aconitum Alkaloids Components into Hydrolysis Monoester-diterpenoid Alkaloids Components and Lipo-alkaloids Components[J].Chemical Research In Chinese Universities,2011,32(3):717-720. |
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| Authors: | LIU Wen-Long LIU Zhi-Qiang SONG Feng-Rui LIU Shu-Ying |
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| Institution: | 1. Changchun Center of Mass Spectrometry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2. Graduate School of Chinese Academy of Sciences, Beijing 100049, China |
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| Abstract: | Methods of specific conversion of diester-diterpenoid aconitum alkaloids components into hydrolysis monoester-diterpenoid alkaloids components and lipo-alkaloids components have been established, conversion percentages were over 90%. Electrospray ionization tandem mass spectrometry was used to monitor conversion degree and identify conversion products, also to detect by-products. |
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| Keywords: | aconitum alkaloids C19-diterpenoid alkaloids electrospray ionization mass spectrometry conversion |
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