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根据角度节面及其对称性分布导出原子轨道形状
引用本文:刘奉岭. 根据角度节面及其对称性分布导出原子轨道形状[J]. 大学化学, 2020, 35(2): 88-91. DOI: 10.3866/PKU.DXHX201905035
作者姓名:刘奉岭
作者单位:山东师范大学化学化工与材料科学学院
基金项目:山东省自然科学基金(ZR2011BM022)
摘    要:原子轨道形状不只由角量子数l决定,也与磁量子数m有关。本文讨论了当l和m的绝对值|m|一定时,如何根据角度节面的数目、形状及角度节面的对称性分布得出原子轨道的图像,同时探讨了原子轨道对称性匹配与原子轨道|m|之间的关系。

关 键 词:原子轨道形状  角量子数l  磁量子数m  对称性
收稿时间:2019-05-14

Derivation of the Shape of an Atomic Orbital from the Angular Nodal Planes and the Symmetries of Their Distribution
Fengling Liu. Derivation of the Shape of an Atomic Orbital from the Angular Nodal Planes and the Symmetries of Their Distribution[J]. University Chemistry, 2020, 35(2): 88-91. DOI: 10.3866/PKU.DXHX201905035
Authors:Fengling Liu
Affiliation:
Abstract:The shape of an atomic orbital not only depends on the azimuthal quantum number l, but also associates with the magnetic quantum number m. We discussed about how to derive the shape of an atomic orbital from the numbers and shapes of the angular nodal planes, and the symmetries of distribution of all angular nodal planes when l and|m|are known. According to the|m|, the compatibility of the symmetry of an atomic orbitals have also been also discussed.
Keywords:Shape of the atomic orbital  Azimuthal quantum number l  Magnetic quantum number m  Symmetry  
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