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Dilatation transformation and sum rules for general potentials including self-consistent field potentials
Authors:L. S. Cederbaum  P. Winkler
Affiliation:(1) Theoretische Chemie, Institut für Physikalische Chemie, Universität Heidelberg, D-69120 Heidelberg, Germany;(2) Present address: Department of Physics, University of Nevada, 89557 Reno, NV, USA
Abstract:The eigenfunctions and energies of general dilated Hamiltonians are expanded in powers of the dilatation parameter. These expansions, augmented by stationarity and stability conditions, are used to derive exact sum rules for bound and resonance states. Particular attention is paid to Hamiltonians with potentials which depend on external parameters, such as the nuclear coordinates in molecules, and to self-consistent potentials. The sum rules can be employed in practical computations to improve the quality of the results and may also serve in analyzing the results from approximate calculations.
Keywords:Dilatation transformation  Sum rules
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