Novel oxovanadium phosphate tubule incorporating 2,2-bipyridine ligands: hydrothermal synthesis and crystal structure of [(V(IV)O)(3)(mu(5)-PO(4))(2)(2,2'-bpy)(mu-OH(2))].1/3H(2)O |
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Authors: | Yang Wenbin Lu Canzhong |
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Institution: | The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, P.R. China. |
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Abstract: | The novel tubular framework of (V(IV)O)(3)(mu(4)-PO(4))(2)(2,2'-bpy)(mu-OH(2))].1/3H(2)O, which was synthesized from hydrothermal reaction, possesses some attractive structural features: (i) O=V(IV)O(4)(OH(2)) octahedra and PO(4) tetrahedra linked together by corner-sharing and face-sharing into a cylinder-shaped channel including 6 water molecules per cell unit, and (ii) (VO)(2,2'-bpy) groups regularly arranged around the tube, so that the 2,2-bpy ligands constitute an organic shell around an aqueous polar channel. |
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