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Synthesis of novel thiazole and pyrrolothiadiazine derivatives from aldehyde thiosemicarbazones
Authors:Mohsen A‐M Gomaa  Alaa A Hassan  Hamdy S Shehatta
Abstract:Substituted thiosemicarbazones 7a–e reacted with ethenetetracarbonitrile (TCNE) in ethyl acetate with formation of 5‐amino‐3‐(substituted ben‐zylidene‐amino)‐2‐phenylimino‐2,3‐dihydrothiazole‐4‐carbonitrile 8a–e 2‐amino‐6‐phenyl‐imino‐1,6‐ dihydropyrrolo1,3,4]thiadiazine‐3‐carbonitrile 9 , and phenyl‐(5‐{substituted phenyl}‐3H‐1,3,4]thiadiazole‐2‐ylidene)amines 10a–e . Rationales for the observed conversations are presented. © 2006 Wiley Periodicals, Inc. Heteroatom Chem 17:261–266, 2006; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20198
Keywords:
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