Two CrIII containing metal‐1‐hydroxyethylidenediphosphonate compounds: Synthesis,structure, and morphology |
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Authors: | Zongbin Wu Zhongmin Liu Peng Tian Lei Xu Haibin Song Xinhe Bao Xiumei Liu Xianchun Liu |
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Abstract: | Two novel layered CrIII containing metal‐hedp compounds, Na20AlCrIIICH3C(O)P2O6]6·O3·(H2O)26·(H3O)10 (CH3 CH2 OH) and Na6CrIIICH3C(OH)P2O6]3·(H2O)21(H3O)3 (designated as DLES‐AlCr and DLES‐CrIII respectively), were hydrothermally synthesized. Their structures were determined by single‐crystal X‐ray diffraction. The two crystals are isostructural with propeller‐like chiral motifs and hexagonal rings along 001]. DLES‐AlCr crystal exhibits interesting hollow tubular hexagonal morphology, while DLES‐Cr crystal possesses solid hexagonal morphology. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) |
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Keywords: | CrIII containing metal‐hedp compounds crystal structure morphology |
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