Validity of energy distribution derived from heat of adsorption in an ammonia/cation-exchanged Y zeolite system |
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Authors: | Y Mitani K Tsutsumi H Takahashi |
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Institution: | (1) Present address: Toyohashi University of Technology, Toyohashi;(2) Institute of Industrial Science, The University of Tokyo, Japan;(3) Present address: Tokuyama Soda Co., Ltd., 745 Tokuyama, Japan |
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Abstract: | The validity of- functions (energy level functions) which were derived from experimentalq- functions (heat functions) was examined in an ammonia/cation-exchanged Y zeolite system. The- functions of Na-Y zeolite and Cs-Na-Y zeolite were respectively calculated from theirq- functions measured by ammonia adsorption at 373 K. The heat of adsorption of ammonia was also measured on a mixture of these two zeolites at a certain mixing ratio at 373 K. The- function of the mixture was likewise calculated on the basis of this measurement. The- function thus calculated was in good agreement with the synthesized- function derived by linearly combining two- functions of each zeolite mentioned above. The- function derived from experimental- function thus proved to be valid in an actual adsorption system. |
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Keywords: | Heat of adsorption energy distribution zeolite |
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