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Palladium-catalyzed direct C-H arylation of unactivated arenes with aryl Halides |
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| Authors: | WenKun Hong Yatao QiuZhiyi Yao Zhaoyang WangSheng Jiang |
| Affiliation: | a Key Laboratory of Regenerative Biology, Guangzhou Institute of Biomedicine and Health, Chinese Academy of Sciences, Guangzhou 510663, China b School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China c Shanghai Institute of Technology, Shanghai 210032, China |
| Abstract: | An efficient palladium-catalyzed direct C-H arylation of unactivated arenes has been discovered. This method employs aryl halides as the direct coupling partners with arenes without using any external ligands. This catalysis opens a new methodology for the preparation of symmetrical as well as unsymmetrical biaryls in a user-friendly approach. |
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