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Synergistic extraction of uranium(VI) with 1-phenyl-3-methyl-4-(2′-chlorobenzoyl)-pyrazolone-5 and acidic organophosphorus reagents
Authors:Mao Jia-Jun  Wang Li-Juan  Chen Yu-De
Institution:(1) Department of Nuclear Science, Fudan University, Shanghai, (People's Republic of China)
Abstract:A study of the synergistic extraction of uranium(VI) from sulphuric acid solution with 1-phenyl-3-methyl-4-(2prime-chlorobenzoyl)-pyrazolone-5 (PMCBP) together with di-(2-ethylhexyl)-phosphoric acid (HDEHP) and also mono-(2-ethylhexyl)-2-ethylhexyl-phosphate (HEHEHP) is described. The results suggest that the compositions of the extracted species is UO2XHA2 and UO2X2H2A2 respectively. Models for the extraction mechanism is also discussed.
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