Cyclotransformation in the series of fused 5-nitropyridin-2(1<Emphasis Type="Italic">H</Emphasis>)-ones |
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Authors: | N N Smolyar Yu M Yutilov |
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Institution: | (1) Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Donetsk, 83114, Ukraine |
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Abstract: | Reactions with excess hydrazine hydrate of 5-nitropyridin-2(1H)-ones fused with benzene, pyridine, and 1,2,3-triazole rings led to a cyclotransformation of the 5-nitro-2-oxopyridine fragment into the 6-methyl-3-oxopyridazine structure. This cyclotransformation is of general character; a probable mechanism of the process is suggested. Details of the assumed mechanism were experimentally confirmed on model compounds. |
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