Synthesis of 2-substituted methylenecycloalkanes from 1-(dialkyl-borylmethyl)cycloalkenes |
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Authors: | Yu N Bubnov L I Lavrinovich |
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Institution: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusions We have developed a novel general method for the preparation of 2-substituted methylenecycloalkanes, which is based upon the allylboration of carbonyl compounds and alkoxyacetylenes by means of hitherto unknown cycloalkenylmethyl(dialkyl)boranes.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, PP. 420–425, February, 1988. |
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