Preparation, characterization and photocatalytic activity of Co3O4/LiNbO3 composite |
| |
| Authors: | Beata Zielinska Magdalena Janus Ryszard J Kalenczuk |
| |
| Institution: | 1235. Institute of Chemical and Environment Engineering, West Pomeranian University of Technology, Szczecin 70-322, Szczecin, Poland
2235. Department of Sanitary Engineering, West Pomeranian University of Technology, Szczecin 70-310, Szczecin, Poland
|
| |
| Abstract: | The Co3O4/LiNbO3 composites were synthesized by impregnation of LiNbO3 in an aqueous solution of cobalt nitrate and next by calcination at 400°C. The activity of produced samples has been investigated in the reaction of photocatalytic hydrogen generation. The crystallographic phases, optical and vibronic properties were studied using X-ray diffraction (XRD), diffuse reflectance (DR) UV-vis and resonance Raman spectroscopic techniques, respectively. The influence of cobalt content (range from 0.5 wt.% to 4 wt.%) on the photocatalytic activity of Co3O4/LiNbO3 composites for photocatalytic hydrogen generation has been investigated. Co3O4/LiNbO3 composites exhibited higher than LiNbO3 photocatalytic activity for hydrogen generation. The highest H2 evolution efficiency was observed for Co3O4/LiNbO3 composite with 3 wt.% cobalt content. The amount of H2 obtained in the presence of LiNbO3 and Co3O4/LiNbO3 (3 wt.% of cobalt content) was 1.38 µmol/min and 2.59 µmol min?1, respectively.  | |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
