Electrochemical synthesis of coatings in the system Ti-Si-B from molten salts |
| |
Authors: | SV Devyatkin |
| |
Institution: | Institute of General and Inorganic Chemistry, Ukrainian National Academy of Science, Palladin avenue 32/34, 03680 Kiev-142, Ukraine |
| |
Abstract: | Powder and coatings of metal-like refractory compounds (MLRC) can be produced by electrochemical synthesis from molten salts. The stoichiometry of the deposited MLRC was found to correlate with the molar ratio of MLRC component ions in the melts. The system Ti-Si-B is of particular interest in terms of electrochemical synthesis since the titanium, silicon and boron potentials in the melt are close together. The electrochemical synthesis has been investigated in the system NaCl-KCl-NaF-K2TiF6-K2SiF6-KBF4 at 700°C. The opportunity of deposition of new ternary compound in the system Ti-Si-B is shown by the electrochemical synthesis from molten salts. |
| |
Keywords: | Ti-Si-B Molten salts Electrochemical synthesis |
本文献已被 ScienceDirect 等数据库收录! |