Hydrothermal synthesis, crystal structure, and magnetic property of a three-dimensional inorganic-organic hybrid material: Mn(H2O)[HO3PCH2NH(CH2CO2)2] |
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| Authors: | Yong Fan Shouhua Feng |
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| Affiliation: | State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Qianwei Road 10, Changchun City, Jilin Province 130012, PR China |
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| Abstract: | A novel three-dimensional inorganic-organic hybrid compound, Mn(H2O)[HO3PCH2NH(CH2CO2)2] from a hydrothermal reaction of Mn (II) ion with N-(phosphonomethyl)iminodiacetic acid (H4PMIDA) was reported. The compound crystallizes in the monoclinic P21/n with cell dimensions of a=5.215(5) Å, b=14.111(15) Å, c=12.727(12) Å, β=93.646(16)°, V=934.6(16) Å3 and Z=4. In this structure each Mn atom is six-coordinated with the carboxylic groups and phosphonic groups to form layers along the bc plane. These layers are further connected with the organic moieties of H2PMIDA, resulting in a complicated three-dimensional network structure. Thermogravimetric analysis, IR spectrum and magnetic susceptibility of this compound are given. |
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| Keywords: | Hydrothermal synthesis Metal phosphonate Structure Property Magnetic susceptibility |
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