Self-assembly of polyoxometalate clusters into a 3-D heterometallic framework via covalent bonding: synthesis, structure and characterization of Na4[Nd8(dipic)12(H2O)9][Mo8O26]·8H2O |
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| Authors: | Enhong Shen Changwen Hu Lin Xu |
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| Institution: | Department of Chemistry, Institute of Polyoxometalate Chemistry, Northeast Normal University, Changchun City, Jilin Province 130024, PR China |
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| Abstract: | An unprecedented hybrid solid obtained by self-assembly of octamolybdate clusters into a three-dimensional alkali metal modified neodymium-organic heterometallic framework is described. Crystal data: monoclinic, space group P21/n,  ,  ,  , β=98.90(3)°;  ; Z=2, R (final)=0.0474. The data were collected on a Rigaku R-AXIS RAPID IP diffractometer at 293 K using graphite-monochromated MoKα radiation ( ) and oscillation scans technique in the range of 1.98°<θ<27.48°. |
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| Keywords: | Hydrothermal synthesis Crystal structure Inorganic-organic hybrid Lanthanide polymolybdate |
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