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Enantioselective acylation of secondary alcohols catalyzed by chiral N-heterocyclic carbenes
Authors:Kano Taichi  Sasaki Kouji  Maruoka Keiji
Institution:Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan.
Abstract:reaction: see text] The synthetic utility of chiral N-heterocyclic carbenes, which have been used mainly in transition metal-catalyzed reactions as a ligand, was demonstrated by the enantioselective acylation of secondary alcohols.
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