Enantioselective acylation of secondary alcohols catalyzed by chiral N-heterocyclic carbenes |
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Authors: | Kano Taichi Sasaki Kouji Maruoka Keiji |
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Institution: | Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan. |
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Abstract: | reaction: see text] The synthetic utility of chiral N-heterocyclic carbenes, which have been used mainly in transition metal-catalyzed reactions as a ligand, was demonstrated by the enantioselective acylation of secondary alcohols. |
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