| 含芳香基的乙二胺四乙酸酰胺衍生物的合成 |
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| 引用本文： | 陈林渺,郝志峰,王雪镅,余坚,余林.含芳香基的乙二胺四乙酸酰胺衍生物的合成[J].合成化学,2010,18(1). |
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| 作者姓名： | 陈林渺 郝志峰 王雪镅 余坚 余林 |
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| 作者单位： | 广东工业大学,轻工化工学院,广东,广州,510006 |
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| 基金项目： | 广东省自然科学基金资助项目 |
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| 摘 要： | 乙二胺四乙酸二酐(1)与氨基芳香酸(2)进行酰化反应,合成了3种新型含芳香基的乙二胺四乙酸酰胺衍生物,其结构经UV,1H NMR,IR和元素分析表征。探讨了反应条件对收率的影响,在最佳反应条件110mmol,n(1)∶n(2)=1∶2,pH 3~4时,于40℃反应12 h]下,收率高于75%。
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| 关 键 词： | 乙二胺四乙酸二酐 氨基芳香酸 酰化反应 合成 |
Synthesis of Ethylene Diamine Tetra-acetic Acid Amide Derivatives with Aromatic Group |
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| CHEN Lin-miao,HAO Zhi-feng,WANG Xue-mei,YU Jian,YU Lin.Synthesis of Ethylene Diamine Tetra-acetic Acid Amide Derivatives with Aromatic Group[J].Chinese Journal of Synthetic Chemistry,2010,18(1). |
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| Authors: | CHEN Lin-miao HAO Zhi-feng WANG Xue-mei YU Jian YU Lin |
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| Abstract: | Three new ethylenediamine tetra-acetic acid amide derivatives with aromatic group were synthesized by acylation reaction of ethylenediamine tetraacetic acid dianhydride(1) and amino aromatic acid(2).The structures were confirmed by UV,~1H NMR,IR and elemental analysis.The effects of reaction conditions on the yield were investigated.The yield was over 75% at 40 ℃ for 12 h under the reaction conditions of 1 10 mol,n(1):n(2)=1:2 and pH 3～4. |
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| Keywords: | ethylenediamine tetraacetic acid anhydride amino aromatic acid acylation reaction synthesis |
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