A yolk-shell nanoreactor with a basic core and an acidic shell for cascade reactions |
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Authors: | Yan Yang Xiao Liu Xiaobo Li Jiao Zhao Shiyang Bai Jian Liu Qihua Yang |
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Affiliation: | State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023 (China) http://www.hmm.dicp.ac.cn. |
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Abstract: | Smart yolk-shell nanoparticles (hollow nanoparticles with a movable core) with an acidic shell and a basic core were fabricated through an organosilane-assisted selective etching method and acted as efficient nanoreactors for catalyzing a deacetalization-Henry cascade reaction with high activity and high selectivity. This strategy is very promising for the design of multifunctional nanoreactors for cascade reactions. |
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Keywords: | cascade reactions yolk–shell nanoparticles acid–base nanoreactors nanostructures |
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