2-Nitroguanidine Derivatives: V. Synthesis and Structure of 3,5-Bis(nitroamino)-1,2,4-triazole Salts. Acid–Base Properties of 3,5-Bis(nitroamino)-1,2,4-triazole |
| |
Authors: | Metelkina E. L. |
| |
Affiliation: | (1) St. Petersburg State Institute of Technology, Moskovskii pr. 26, St. Petersburg, 190013, Russia |
| |
Abstract: | Heterocyclization of hydrazine-1,2-bis(N2-nitrocarboximidamide) and salts derived therefrom provides a procedure for the synthesis of 3,5-bis(nitroamino)-1,2,4-triazole salts. The presence of two acceptor nitroamino groups conjugated with the triazole ring considerably enhances the acidity of 3,5-bis(nitroamino)-1,2,4-triazole (pK a1= –2.0, pKa2 = 4.8, pKa3 = 10.6) as compared to mononitroaminotriazole, so that formation of salts with the corresponding dianion becomes possible. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|