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Enantioselective Pd-catalyzed hydrogenation of enesulfonamides
Authors:Yu Chang-Bin  Gao Kao  Wang Duo-Sheng  Shi Lei  Zhou Yong-Gui
Institution:State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China.
Abstract:Asymmetric hydrogenation of cyclic enesulfonamides affords chiral cyclic sulfonamides using Pd(OCOCF(3))(2)/diphosphine complexes as catalysts with up to 98% ee.
Keywords:
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