Enantioselective Pd-catalyzed hydrogenation of enesulfonamides |
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Authors: | Yu Chang-Bin Gao Kao Wang Duo-Sheng Shi Lei Zhou Yong-Gui |
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Institution: | State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China. |
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Abstract: | Asymmetric hydrogenation of cyclic enesulfonamides affords chiral cyclic sulfonamides using Pd(OCOCF(3))(2)/diphosphine complexes as catalysts with up to 98% ee. |
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