Electrochemical synthesis of halogen derivatives of bis(1,2-dicarbollyl)cobalt(III) |
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| Authors: | D A Rudakov V L Shirokii V A Knizhnikov A V Bazhanov E I Vecher N A Maier V I Potkin A N Ryabtsev P V Petrovskii I B Sivaev V I Bregadze I L Eremenko |
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| Institution: | (1) Institute of Physical Organic Chemistry, Belarus National Academy of Sciences, 13 ul. Surganova, 220072 Minsk, Belarus;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation;(3) N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991 Moscow, Russian Federation |
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| Abstract: | A convenient electrochemical method for the synthesis of 8,8 -dihalogen derivatives of bis(1,2-dicarbollyl)cobalt(III) anion 8,8X2-3,3-Co(1,2-C2B9H10)]– (X = Cl, Br, I) was developed. The method includes the electrolysis of a solution of alkaline metal halide and tetramethylammonium salt of bis(1,2-dicarbollyl)cobalt(III) in methanol at 50 °C in a one-compartment electrochemical cell with a nickel cathode and platinum anode.__________Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2448–2451, November, 2004. |
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| Keywords: | III)" target="_blank">bis(dicarbollyl)cobalt(III) halogenation electrochemistry |
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