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钙钛矿太阳电池吸光层材料研究进展
引用本文:晒旭霞,李丹,刘双双,李浩,王鸣魁.钙钛矿太阳电池吸光层材料研究进展[J].物理化学学报,2016,32(9):2159-2170.
作者姓名:晒旭霞  李丹  刘双双  李浩  王鸣魁
作者单位:
基金项目:The project was supported by the Natural Science Foundation of Hubei Province, China(ZRZ2015000203);Technology Creative Project of Excellent Middle & Young Team of Hubei Province, China(T201511)
摘    要:近年来,有机-无机卤化铅钙钛矿太阳电池的研究取得了突破性进展,公证记录电池效率22.1%,与CdTe薄膜电池(认证记录电池效率22.1%)和CuInGaSn(CIGS)(认证记录电池效率22.3%)薄膜电池技术相媲美,已经接近于市场上主导地位的晶体硅太阳电池(约25%)。有机卤化铅钙钛矿太阳电池器件的长期效率输出稳定性和含毒性Pb严重制约其实际应用。本文将讨论有机卤化铅钙钛矿太阳电池不稳定性因素和相应的解决方案,并对钙钛矿材料中Pb元素的取代工作和无机非铅钙钛矿材料及其太阳电池的研究进行了阐述与展望。

关 键 词:钙钛矿  稳定性  Pb取代  太阳电池  无机非铅钙钛矿  
收稿时间:2016-04-12

Advances and Developments in Perovskite Materials for Solar Cell Applications
Xu-Xia SHAI,Dan LI,Shuang-Shuang LIU,Hao LI,Ming-Kui WANG.Advances and Developments in Perovskite Materials for Solar Cell Applications[J].Acta Physico-Chimica Sinica,2016,32(9):2159-2170.
Authors:Xu-Xia SHAI  Dan LI  Shuang-Shuang LIU  Hao LI  Ming-Kui WANG
Institution:
Abstract:In recent years, significant breakthroughs have been achieved in the development of organicinorganic halide lead perovskite solar cells, with reported power conversion efficiency (PCE) values of up to 22.1%. This value is comparable to the efficiencies obtained using CdTe (22.1%) and CuInGaSn (CIGS) (22.3%) solar cells, and close to the value associated with crystalline silicon solar cells (approximately 25%). However, the limited long-term output efficiency stability and lead toxicity issues associated with organic-inorgan lead halide perovskite cells have limited their commercial applications. This review focuses on these issues and corresponding solutions for halide lead hybrid perovskite solar cells, and discusses advances and developments in Pb-free inorganic perovskite solar cells. We also examine the current body of knowledge regarding perovskite solar cells and discuss critical points and expectations regarding further performance improvements.
Keywords:Perovskite  Stability  Pb substitution  Solar cell  Pb-free inorganic perovskite  
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