Über den Mechanismus der Cope-Umlagerung |
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| Authors: | Rudolf Wehrli Hans Schmid Daniel Bellu
Hans-Jürgen Hansen |
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| Institution: | Rudolf Wehrli,Hans Schmid,Daniel Belluŝ,Hans-Jürgen Hansen |
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| Abstract: | On the Mechanism of the Cope Rearrangement The rates of the Cope rearrangement of 2,5-dicyano-3-methyl-hexa-1, 5-diene ( 12 ), (E)- and (Z)-2, 5-dicyano-hepta-1,5-diene ((E)- and (Z)- 14 ) as well as of 2, 5-dimethoxycarbonyl-3-methyl-hexa-1,5-diene ( 13 ) and (E)- and (Z)-2,5-dimethoxycarbonyl-hepta-1,5-diene ((E)- and (Z)- 15 ) were measured in decane solution in the temperature range of 50 to 150° (see Tables 5 and 8 to 12). A detailed English summary of this work is given in 1 b]. |
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