Mulliken-Hush analysis of a bis(triarylamine) mixed-valence system with a N...N distance of 28.7 A |
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| Authors: | Heckmann Alexander Amthor Stephan Lambert Christoph |
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| Institution: | Institute of Organic Chemistry, University of Würzburg, Am Hubland, D-97074 Würzburg, Germany. lambert@chemie.uni-wuerzburg.de. |
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| Abstract: | An organic mixed valence compound with a spacer length of 25 unsaturated bonds separating two amine redox centres was synthesised and the electron transfer behaviour was investigated in the context of a Mulliken-Hush analysis in order to estimate the longest redox centre separation for which an intervalence charge transfer band can be observed. |
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