Copper(II) complex with 2-(diphenylacetyl)indanedione-1,3: Synthesis and structure |
| |
Authors: | A. N. Kochetov L. G. Kuz’mina |
| |
Affiliation: | (1) Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571, Russia;(2) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia |
| |
Abstract: | A copper(II) complex with 2-(diphenylacetyl)indanedione-1,3 (HL) was synthesized. CuL2·0.5C4H8O2 crystals prepared from chloroform + 1,4-dioxane are triclinic, space group P (bar 1), a = 15.0206(9) Å, b = 16.0132(9) Å, c = 16.8323(10) Å, α = 109.6850(10)°, β = 96.4390(10)°, γ = 97.7120(10)°, Z = 4. A unit cell contains two crystallographically independent centrosymmetric dinuclear complexes of the same structure. Each copper(II) atom is coordinated by bidentate cis-oriented deprotonated ligands L at the corners of the square. Bridging 1,4-dioxane molecules make the CN of each metal atom five. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|