Copper(II) complex with 2-(diphenylacetyl)indanedione-1,3: Synthesis and structure |
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| Authors: | A N Kochetov L G Kuz’mina |
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| Institution: | (1) Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571, Russia;(2) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia |
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| Abstract: | A copper(II) complex with 2-(diphenylacetyl)indanedione-1,3 (HL) was synthesized. CuL2·0.5C4H8O2 crystals prepared from chloroform + 1,4-dioxane are triclinic, space group P \(\bar 1\), a = 15.0206(9) Å, b = 16.0132(9) Å, c = 16.8323(10) Å, α = 109.6850(10)°, β = 96.4390(10)°, γ = 97.7120(10)°, Z = 4. A unit cell contains two crystallographically independent centrosymmetric dinuclear complexes of the same structure. Each copper(II) atom is coordinated by bidentate cis-oriented deprotonated ligands L at the corners of the square. Bridging 1,4-dioxane molecules make the CN of each metal atom five. |
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