过渡金属催化不饱和烃与二氧化碳的羧化反应研究与进展

CO₂是一种无毒、廉价易得、储量丰富的可再生资源,通过化学方法将其转化为具有高附加值的化学品已成为实现可持续发展的战略性课题。其中,以CO₂作为羧化试剂合成羧酸及其衍生物的研究已成为CO₂催化活化领域的研究热点。本文按照不同过渡金属催化的不饱和烃与CO₂的羧化反应,分类归纳了近些年来的羧化反应研究进展。

Transition-metal catalyzed carboxylation of unsaturated hydrocarbons with CO2

The chemical conversion of carbon dioxide, a non-toxic, non-flammable, abundant and cheap renewable C1 resource, into high value-added organic compounds has become an important strategy for sustainable development. Among various transformations, CO₂ as the carboxylating agent for the synthesis of carboxylic acids and derivatives has attracted much attention in the activation and conversion of CO₂ field. This review summarizes the carboxylation of unsaturated hydrocarbons with CO₂ catalyzed by transition-metal catalysis in recent years.