Darstellung, eigenschaften und kristallstruktur von methylgalliumdiacetat CH3Ga(OOCCH3)2 |
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Authors: | H D Hausen K Sille J Weidlein W Schwarz |
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Institution: | Institut für Anorganische Chemie der Universität Stuttgart, Pfaffenwaldring 55, 7 Stuttgart 80 Deutschland |
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Abstract: | Trimethylgallium reacts with acetic acid in a molar ratio yielding methylgallium diacetate, CH3Ga(OOCCH3)2? The structure is determined by vibrational spectroscopy and the crystal structure is described. Methylgallium diacetate crystallizes in the monoclinic space group P21/c with lattice constants a 776.5, b 1428.9, c 1406.3 pm, β 91.87° and eight formula units per cell. The monomers are linked together by acetate groups forming polymeric, waved layers. Besides the bridging acetate there are also “free” acetate groups coordinated at the distorted trigonal-bipyramidal coordinated Ga(1) atom. A second gallium atom Ga(2) is coordinated distorted tetrahedrally, the acetate groups bonded to Ga(2) being all bridging. The mean intermolecular distances are: GaC 194.6 pm, Ga(1)Oapical 215.3 pm, Ga(1)Oeq(bridge) 194.3 pm, Ga(1)Oeq(free) 187.3 pm, Ga(2)O 191.3 pm, CC 151.5 pm, CO 119.4 pm, CO 131.1 pm, CO 127.3 pm. |
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