| 芳香化合物离子的电子自旋共振波谱 |
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| 引用本文： | 裘祖文,王文韵,张守信. 芳香化合物离子的电子自旋共振波谱[J]. 物理学报, 1963, 19(9): 583-598 |
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| 作者姓名： | 裘祖文 王文韵 张守信 |
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| 摘 要： | 本文报导在ЭПР-2 975千周高频调制波谱仪中得到的近30个芳香离子的电子自旋共振波谱。多数离子具有分辨良好的超精细结构。部分离子可以用McConnellσ-π构相互作用理论和Hückel L.C.A.O.-M.O.理论计算得理论图。比较理论图和实验结果,作者认为两者的符合程度是比较满意的。
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| 收稿时间： | 1962-12-10 |
THE ELECTRON SPIN RESONANCE SPECTRA OF AROMATIC IONS |
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| CHIU TSU-WEN,WANG WEN-YUN and CHANG SU-SHIN. THE ELECTRON SPIN RESONANCE SPECTRA OF AROMATIC IONS[J]. Acta Physica Sinica, 1963, 19(9): 583-598 |
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| Authors: | CHIU TSU-WEN WANG WEN-YUN CHANG SU-SHIN |
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| Abstract: | In this article, about 30 aromatic ions have been studied with the элр-2 975 Kc high frequency modulation spectrometer. Most of them show well resolved hyperfine patterns. Part of them is compared with the theoretical hyperfine patterns deduced from the McConnell's σ-π configurational interaction theory and Hückel L.C.A.O.-M.O. theory. The coincidence between experimental and theoretical patterns is considered to be satisfactory. |
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