|
|||||
|
|
Phenyldioxaborolane promoted synthesis of bisphosphine compounds |
|
| Authors: | Yin-Wei SunPeng-Long Zhu Qin Xu |
| Affiliation: | a Key Laboratory for Advanced Materials and Institute of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science and Technology, 130 Mei-Long Road, Shanghai 200237, China b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China |
| Abstract: | Bisphosphine compounds have a wide range of applications. In this paper, we reported that bisphosphine compounds could be prepared in moderate to good yields from dialkyl acylphosphonates under mild conditions in the presence of phenyldioxaborolane and potassium hydroxide via a C-P bond cleavage and a subsequent 1,2-migration of phosphoryl group. |
| Keywords: | Phenyldioxaborolane Arylboronic acids Bisphosphine compounds Phosphoryl group migration |
| 本文献已被 ScienceDirect 等数据库收录！ | |