Unexpected formation of clusters with a nortricyclene-containing carborane ligand, 1-(η6-arene)-3-(C7H9CH2O)-isonido-1,2,4-RuC2B8H9, in the reaction of 1,1,3-(PPh3)3-1-H-1,2,4-RuC2B8H9 with 2-(hydroxymethyl)norbornadiene in arene solvents期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Unexpected formation of clusters with a nortricyclene-containing carborane ligand, 1-(η6-arene)-3-(C7H9CH2O)-isonido-1,2,4-RuC2B8H9, in the reaction of 1,1,3-(PPh3)3-1-H-1,2,4-RuC2B8H9 with 2-(hydroxymethyl)norbornadiene in arene solvents

Authors:	Konoplev V. E. Dolgushin F. M. Pisareva I. V. Vorontsov E. V. Lemenovskii D. A. Chizhevsky I. T.

Affiliation:	1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation 2. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119992, Moscow, Russian Federation

Abstract:	Heating of 1,1,3-(PPh₃)₃-1-H-1,2,4-RuC₂B₈H₉ with 2-(hydroxymethyl)bicyclo[2.2.1]hepta-2,5-diene in arene solvents (benzene, toluene, or mesitylene) unexpectedly afforded the ruthenium arene complexes 1-(η⁶-arene)-3-(C₇H₉CH₂O)-isonido-1,2,4-RuC₂B₈H₉ containing the nortricyclene fragment in the carborane ligand.

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