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Periodic mesoporous organosilica from zwitterionic precursors
Authors:El Hankari Samir  Motos-Pérez Blanca  Hesemann Peter  Bouhaouss Ahmed  Moreau Joël J E
Affiliation:Institut Charles Gerhardt de Montpellier, UMR CNRS 5253, Ecole Nationale Supérieure de Chimie de Montpellier, 8 rue de l'Ecole Normale, 34296 Montpellier Cedex 05, France.
Abstract:Mesoporous hybrid silica bearing zwitterionic species were synthesized via template-directed hydrolysis-polycondensation reactions from zwitterionic ammonium sulfonate precursors. The formation of the nanostructured phases involves specific precursor-template interactions. The obtained materials are efficient heterogeneous catalysts in Biginelli reactions.
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