Solid state precursor strategy for synthesizing hollow TiO2 boxes with a high percentage of reactive {001} facets exposed |
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| Authors: | Xie Shuifen Han Xiguang Kuang Qin Fu Jie Zhang Lei Xie Zhaoxiong Zheng Lansun |
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| Affiliation: | State Key Laboratory for Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, PR China. |
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| Abstract: | Three-dimensional, hollow, anatase TiO(2) boxes, each was enclosed by six single-crystalline TiO(2) plates exposed with highly reactive {001} facets, were facilely obtained by calcining a cubic TiOF(2) solid precursor at 500-600 °C. The formation of such particular nanostructures is attributed to the hard self-template restriction and the adsorption of F(-) ions from the TiOF(2). |
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