| A New Cadmium（II） Coordination Polymer Constructed by 2-（2-Chloro-6-fluorophenyl）-lH-imidazo[4,5-f] [1, 10]phenanthroline and 1,2,3-Benzenecarboxylate： Synthesis,Structure and Luminescence |
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| 作者姓名： | WANG Xiu-Yan LIU Fu-Yi ZHANG Yan-Na GENG Li-Rong ZHOU Hao XU Zhan-Lin |
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| 作者单位： | [1]Key Laboratory of Preparation andApplications of Environmental Friendly Materials, Jilin Normal University, Siping 136000, China [2]Department of Chemistry, Jilin Normal University, Siping 136000, China |
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| 基金项目： | Supported by the Science and Technology Research Projects of the Education Committee of Jilin Province （No. 2013212） |
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| 摘 要： | A new Cd（II） coordination polymer, namely, [Cd3（1,2,3-BTC）2（L）2]·2.25H2O （1, L = 2-（2-chloro-6-fluorophenyl）-1H-imidazo[4,5-A][1,10]phenanthroline and 1,2,3-BTC = 1,2,3-ben- zenetricarboxylate）, has been synthesized under hydrothermal conditions. The compound was characterized by single-crystal X-ray diffraction. It crystallizes in triclinic, space group Pī with α = 11.650（2）, b = 12.240（2）, c = 19.760（4） A, α = 72.01（3）, β = 77.11（3）, γ = 83.48（3）°, V = 2609.4（9） A3, Z = 2, C56H31Cd3Cl2F2N8O14.25, Mr = 1489.99, Dc = 1.896 g/cm3, F（000） = 1466, μ（MoKa） = 1.401 mm^-1, R = 0.0401 and wR = 0.1104. Compound 1 shows a 1D chain structure, and the neigh- boring 1D chains of 1 are joined together by π···π interactions to result in a 2D supramolecular layer. In addition, the luminescent property of 1 has been studied in the solid state at room temperature.
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| 关 键 词： | 配位聚合物 镉（Ⅱ） 发光特性 链结构 咪唑 苯基 合成 菲罗啉 |
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