Multiple reaction scheme modelling |
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Authors: | J P Elder |
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Institution: | 1. Merck and CO., Inc., P.O. Box 2000, 07065-0900, Rahway, NJ, USA
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Abstract: | A simple procedure whereby the energies of activation and pre-exponential factors of the individual reactions, of any kinetic model, comprising a wide variety of multiple reaction sets, is described. The sets belong to one of three classes, such that the single extent of reaction—temperature curves diverge, converge or are equally spaced at one prescribed temperature. The method has been applied to sets of first order reactions, which yield effectiven th order reactions with the order ‘n’varying from ~0.6 to ~ 3.0. Variations in Friedman iso-conversional reaction kinetics analytical data are indicative of the designed reaction complexity. |
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