Reaction of carboxylic acid esters with phenolates in oil-in-water microemulsions based on cetyltrimethylammonium bromide |
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| Authors: | A. B. Mirgorodskaya F. G. Valeeva L. A. Kudryavtseva N. N. Vylegzhanina Yu. F. Zuev |
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| Affiliation: | (1) Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, Kazan, ul. Arbuzova 8, Tatarstan, 420088, Russia;(2) Institute of Biochemistry and Biophysics, Kazan Research Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia |
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| Abstract: | A kinetic study of reactions of carboxylic acid esters with phenols activated with alkalis or amines in microemulsions based on cationic surfactants showed that the phenolates formed upon activation exhibit different nucleophilicity depending on the value of the negative charge on the oxygen atom, which is determined by the properties of the phenol, ionizing agent, and solvent. |
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