Luminescent properties of Yb-doped LaSc3(BO3)4 under VUV excitation |
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Affiliation: | 1. Physics Department, M.V. Lomonosov Moscow State University, Leninskie gory, 119992 Moscow, Russia;2. Laser Crystals Department, General Physics Institute of RAS, Vavilova str. 38, 119991 Moscow, Russia;3. Laboratoire de Physico-Chimie des Materiaux Luminescents, Universite Claude Bernard Lyon-1, UMR 5620 CNRS, 69622 Villeurbanne, France |
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Abstract: | Ytterbium doped borate crystals are promising laser media, e.g. in (LSB) matrices large distance between ytterbium ions results in reduced concentration quenching of the ytterbium f–f luminescence [Petermann, K., Fagundes-Peters, D., Johansen, O., Mond, M., Peters, V., Romero, J.J., Kutovoi, S., Speiser, J., Giesen, A., 2005. Highly Yb-doped oxides for thin-disc lasers. J. Crystal Growth 275, 135-140]. ions in complex oxides in addition to the 4f 4f transitions often manifest fast charge transfer luminescence (CTL) in the UV-visible range. In some borates it was not observed at all, like in orthoborates of Sc, Y and La [Van Pieterson, L., Heeroma, M., de Heer, E., Meijerink, A., 2000. Charge transfer luminescence of . J. Lumin. 91, 177–193]; in haloborates , where X = Cl, Br, the UV/visible luminescence was attributed to ytterbium CTL though it looked substantially different from other matrices [Dotsenko, V.P., Berezovskaya, I.V., Pyrogenko, P.V., Efryushina, N.P., Rodniy, P.A., Eijk van, C.W.E., Sidorenko, A.V., 2002. Valence states and luminescence properties of ytterbium ions in strontium haloborates. J. Solid State Chem. 166, 271–276]; while in oxyborate “classical” CTL was observed [Jubera, V., Garcia, A., Chaminade, J.P., Guillen, F., Sablayrolles, Jean, Fouassier, C., 2007. and luminescent properties of the phase. J. Lumin. 124(1), 10–14]. In this work the luminescence properties of another borate, namely LSB doped by Yb are presented. |
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