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Infrared reflection spectra of selected modifications of SiO2 and Al2O3
Authors:Franti&#x;ek Pechar
Abstract:Infrared reflection spectra were measured within the wave number range of 1400 – −400 cm−1 for following SiO2 and Al2O3 modifications: quartz, opal, quartz glass, cristobalite, tridymite, corundum, sapphire, ruby, gibbsite, boehmite, and diaspore. The spectral bands were attributed, according to literature quotations, to individual vibrations of bonds Si O, O Si O, Si O Si, Al O, O Al O, and Al O Al. The evaluation of infrared reflection spectra has shown that they are very sensitive to internal vibrations of Si O, Al O, which are affected by the symmetry of the surrounding crystal field. They are therefore selective for individual minerals and thus suitable for quick identifying purposes.
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