Stereoselective synthesis of (+)-polyoxamic acid based on the synthesis of chiral oxazine |
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| Authors: | Joo Jae-Eun Pham Van-Thoai Tian Yong-Shou Chung Yun-Sung Oh Chang-Young Lee Kee-Young Ham Won-Hun |
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| Affiliation: | College of Pharmacy, SungKyunKwan University, Suwon, 440-746, Korea. |
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| Abstract: | A concise, stereocontrolled synthesis of (+)-polyoxamic acid was achieved. Starting from trans-oxazoline as a chiral building block, the key step involves diastereoselective oxazine formation catalyzed by palladium(0). |
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