Curing effects on the acoustical properties of epoxy polymers

This paper presents an experimental method for measuring the attenuation and the velocity of longitudinal ultrasonic waves propagating through flat epoxy polymer samples. The study takes place in the first phase of epoxy polymer's polymerization, where these materials pass slowly from liquid state to the solid state. For this purpose an experimental setup was introduced, suitable for the accurate evaluation of the acoustic properties Δα andc _ℓ ^e , when the epoxy polymers are in their first phase of polymerization, while they are cured for 24 hours at room temperature (20°C). The ultrasonic method used is the pulse echo-through transmission technique. From the variation ofc _ℓ ^e and Δα during the first phase of epoxy polymers curing, the three characteristic states: liquid, semi-solid and solid, are clearly determined. It is also observed that plasticizer reduces the testability and the semi-solid state shows greater attenuation than either the liquid or the solid state.