Oxidative dihydroxylation of alicyclic unsaturated hydrocarbons with vinyl- and norbornene fragments in pseudohomogenic system |
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Authors: | Kh. M. Alimardanov N. I. Garibov M. Ya. Abdullaeva O. A. Sadygov A. D. Kuliev E. G. Ismailov |
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Affiliation: | 1. Mamedaliev Institute of Pertochemical Processes, National Academy of Sciences of Azerbaijan, Khojaly avenue 30, Baku, 1025, Azerbaijan
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Abstract: | Oxidation of alicyclic unsaturated hydrocarbons (4-vinylcyclohexene, 5-vinylnorbornene, 5-cyclohexenylnorbornene, and 5-vinylbicyclooctene) with 30% hydrogen peroxide solutions and percarbamide is studied. Reaction was carried out at 40–70°C in the presence of heterogenized peroxocomplex compounds of molybdenum and tungsten formed “in situ” in the reaction of metal oxohalides with H3PO4, nano-dimensional particles of carbon material, and hydrogen peroxide. Main oxidation products of alicyclic diene hydro-carbons are the corresponding unsaturated epoxides and diols. Depending on the reaction condition their ratio varies in a wide range. |
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